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純度：98% |
包裝：25kg/桶 |
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結構式
CAS: 128-09-6
分子式: C4H4ClNO2
分子量: 133.53
中文名稱: N-氯代丁二酰亞胺
琥珀酰氯亞胺
氯代二乙酰亞胺
氯代琥珀酰亞胺
N-氯丁二酰亞胺
氯代丁二酰亞胺
琥珀酰基氯亞胺
N-氯代二乙酰亞胺
N-氯代琥珀酰亞胺
英文名稱: N-Chlorosuccinimide
Succinchlorimide
1-chloro-2,5-pyrrolidinedione
1-chloro-5-pyrrolidinedione
chlorosuccinimide
ncs
性質描述: 白色單斜結晶。熔點150-151℃，1g-產品約溶于70ml水、150ml醇、50ml苯，稍溶于醚、氯仿和四氯化碳。1：50-氯代丁二酰亞胺水溶液對石蕊呈酸性。有氯的氣味。
產品質量
指標名 指標
外觀 淺黃至白色晶體
含量 98%
有效氯 ≥26
熔點 148-153(℃)
干燥失重 ≤1%
硫分 ≤0.2%
自由酸 ≤0.02%
用途: 精細化工產品。在醫藥工業中，是合成炔諾酮，16-次甲基氯地孕酮，舒經藥，多西環素和甲烯土霉素等藥物的中間體。在有機反應中可用作氯化試劑。
其它信息：
Product Identification
【Product Name】Chlorosuccinimide N-氯代丁二酰亞胺
【Synonyms】
1-Chloro-2,5-pyrrolidinedione
1-Chloropyrrolidine-2,5-dione
Chlorosuccinimide
Succinchlorimide
【CAS】128-09-6
【Formula】C4H4ClNO2
【Molecular Weight】133.53
【EINECS】204-878-8
【RTECS】UY1013500
【RTECS Class】Tumorigen
【Merck】13,2183
【Beilstein/Gmelin】113915
【Beilstein Reference】5-21-09-00543
【EC Class】harmful, corrosive
Physical and Chemical Properties
【Appearance】White crystalline powder. Odor of chlorine odor.
【Solubility in water】Very soluble
【Boiling Point】216.5
【Vapor Pressure】0.3 (25 C)
【Density】1.65 g/cm3
【Partition Coefficient】-0.87
【Heat Of Vaporization】43.7
【Usage】Chlorinating agent.
First Aid Measures
【Ingestion】Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
【Skin】Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
【Eyes】Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Handling and Storage
【Storage】Store in a cool, dry place. Do not store in direct sunlight. Store in a tightly closed container. Store protected from moisture.
【Handling】Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Do not get on skin or in eyes. Do not ingest or inhale.
Hazards Identification
【Ingestion】May cause severe gastrointestinal tract irritation with nausea, vomiting and possible burns.
【Inhalation】May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema. The toxicological properties of this substance have not been fully investigated.
【Skin】May cause severe irritation and possible burns.
【Eyes】Contact with eyes may cause severe irritation, and possible eye burns.
【Hazards】Contact with metals may evolve flammable hydrogen gas.
【EC Risk Phrase】R 22 34
【EC Safety Phrase】S 26 36/37/39 45
【UN (DOT)】1759
Exposure Controls/Personal Protection
【Personal Protection】Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Fire Fighting Measures
【Flash Point】75
【Fire Fighting】Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam. Use agent most appropriate to extinguish fire.
【Fire Potential】Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Accidental Release Measures
【Small spills/leaks】Vacuum or sweep up material and place into a suitable disposal container. Reduce airborne dust and prevent scattering by moistening with water. Clean up spills immediately, using the appropriate protective equipment. Provide ventilation.
Stability and Reactivity
【Disposal Code】3
【Stability】Stable at room temperature in closed containers under normal storage and handling conditions.
【Incompatibilities】Strong oxidizing agents, strong bases, amines, strong acids, ammonia, iron, and iron salts. Explosive reaction with aliphatic alcohols, benzylamine, and hydrazine hydrate.
【Decomposition】Hydrogen chloride, chlorine, nitrogen oxides, carbon monoxide, carbon dioxide.
【Combustion Products】Fire may produce irritating, corrosive and/or toxic gases.
Transport Information
【UN Number】1759
【Hazard Class】8
【Packing Group】I; II; III
【HS Code】2925 19 95 |
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